a study for the synthesis of dibenzo [a,j] xanthenes and 1-amidoalkyl 2-naphthols catalyzed by [hmim][hso4] as a green, efficient and reusable catalyst under solventfree conditions
نویسندگان
چکیده
a convenient and efficient procedure for the synthesis of 14-aryl or alkyl-14h-dibenzo[a,j]xanthenes by condensation of 2-naphthol and aldehydes in the presence of methylimidazolium hydrogensulfate, as a brönsted acidic ionic liquid ([hmim]hso4), is described. both aromatic and aliphatic aldehydes reactedeasily to afford the corresponding 14-aryl or alkyl-14h-dibenzo[a,j]xanthenes in good yields under solvent-free conditions. moreover, the synthesis of 1-amidoalkyl 2-naphthols is studied by condensation of aromatic aldehydes with amides or urea and 2-naphthol in the presence of [hmim]hso4. using solventfreeconditions, non-toxic and inexpensive materials, simple and clean work-up, short reaction times and high yields of the products are the advantages of this method.
منابع مشابه
A study for the synthesis of dibenzo [a,j] xanthenes and 1-amidoalkyl 2-naphthols catalyzed by [Hmim][HSO4] as a green, efficient and reusable catalyst under solventfree conditions
A convenient and efficient procedure for the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes by condensation of 2-naphthol and aldehydes in the presence of Methylimidazolium hydrogensulfate, as a Brönsted acidic ionic liquid ([Hmim]HSO4), is described. Both aromatic and aliphatic aldehydes reacted easily to afford the corresponding 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes in good yiel...
متن کاملA study for the synthesis of dibenzo [a,j] xanthenes and 1-amidoalkyl 2-naphthols catalyzed by [Hmim][HSO4] as a green, efficient and reusable catalyst under solventfree conditions
A convenient and efficient procedure for the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes by condensation of 2-naphthol and aldehydes in the presence of Methylimidazolium hydrogensulfate, as a Brönsted acidic ionic liquid ([Hmim]HSO4), is described. Both aromatic and aliphatic aldehydes reacted easily to afford the corresponding 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes in good yiel...
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چکیده ندارد.
A fast, simple and convenient procedure for the synthesis of fused pyrimidinone derivatives by using [Hmim][HSO4] as a green, efficient and reusable catalyst under solvent-free conditions
In the present of methylimidazolium hydrogen sulfate, the synthesis of arylidene heterobicyclic pyrimidinones is studied by condensation of aromatic aldehyde, cyclopentanone, and urea or thiourea. Using solvent-free conditions, non-toxic and inexpensive materials, simple and clean work-up, short reaction times and good yields of the products are the advantages of this method.
متن کاملA fast, simple and convenient procedure for the synthesis of fused pyrimidinone derivatives by using [Hmim][HSO4] as a green, efficient and reusable catalyst under solvent-free conditions
In the present of methylimidazolium hydrogen sulfate, the synthesis of arylidene heterobicyclic pyrimidinones is studied by condensation of aromatic aldehyde, cyclopentanone, and urea or thiourea. Using solvent-free conditions, non-toxic and inexpensive materials, simple and clean work-up, short reaction times and good yields of the products are the advantages of this method.
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Nanosilica periodic acid (nano-SPIA) is found to be a new, powerful, and reusable heterogeneous catalyst for the rapid synthesis of 2-naphtholazo dyes via diazotization of aromatic amines and followsazo coupling with 2-naphthol under solvent-free conditions at room temperature by grinding. Eco-friendly, heterogeneous reaction conditions, high stability of diazonium salt, simple experimental pro...
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عنوان ژورنال:
iranian journal of catalysisناشر: islamic azad university, shahreza branch
ISSN 2252-0236
دوره 1
شماره 1 2011
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